Abstract:
We measured the spatial damping of low-frequency surface waves at air-water interfaces using a novel heterodyne light scattering technique. For pure water the measured damping agrees well with linear hydrodynamic theory. For interfaces covered with a monolayer of pentadecanoic acid, we find a five-fold increase in damping at a surface concentration of 2.2 molecules nm-2, near the high-density end of the gas/liquid-expanded coexistence region. The behavior of the damping as a function of surface concentration cannot be explained by existing theories.